"We reiterate unrestrictedly our obedience, subordination and loyalty" to President Nicolas Maduro, he added. Maduro faces calls to quit as his country struggles with shortages of food and medicine. The military high command has so far maintained its public backing for Maduro - seen as key to keeping him in power.
Guaido, leader of the Venezuelan legislature, has declared himself acting president and is appealing to military leaders to switch allegiance to him.
He is backed by the United States and some 50 other countries. The United States has sent food and medical aid for Venezuela but the military has so far refused to let it enter the country.