Organisers said the world No 8 would join compatriots Stuart Appleby, Robert Allenby, Nick O'Hern, Rod Pampling and defending champion Richard Green in the December 8-11 tournament.
Scott, 25, has 10 international tour victories in his five-year professional career, three of those coming this year in the Nissan Open on the US Tour, the European Tour-sanctioned Johnnie Walker Classic in Beijing and the Singapore Open by seven strokes. Scott finished runner-up at Huntingdale in 2002 and 2003 but was denied on both occasions in a sudden-death play-off.